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Re:Aluminum formate Al(HCOO)3: Earth-abundant, scalable, & m... by brilee on Monday November 07, 2022 @08:16AM (#33505375)
Chemist here.

Formate does indeed act as a reducing agent under appropriate conditions, but its byproduct is typically CO2 gas, not formaldehyde (HCOO- -> CO2 + H+ + 2e-). Aldehydes are generally unstable with respect to disproproportionation and are therefore unlikely reaction products.

Organoaluminum compounds are molecules with direct Al-C bonds, whereas these are effectively normal ionic salts with some unusual unit cell structure. Conflating DiBAl with aluminum formate is akin to conflating chlorine gas with clhoride anion...

Re:Aluminum formate Al(HCOO)3: Earth-abundant, scalable, & m... by refurb on Monday November 07, 2022 @09:01AM (#33505858)
Formate ions can disproportionate:

HCO2H -> CO2 + H2

HCO2H + H2 -> HCHO + H2O

However, aluminum salts of formate are likely more stable? You usually need formic acid and heat to generate hydrogen.

Re:Aluminum formate Al(HCOO)3: Earth-abundant, scalable, & m... by kragen on Monday November 07, 2022 @09:10AM (#33505946)
also if you get trace amounts of formaldehyde out the smokestack it isn't going to last more than a few hours in the environment. every living thing produces formaldehyde