Re:Aluminum formate Al(HCOO)3: Earth-abundant, scalable, & m...
by refurb on Monday November 07, 2022 @09:01AM
(#33505858)
Formate ions can disproportionate:
HCO2H -> CO2 + H2
HCO2H + H2 -> HCHO + H2O
However, aluminum salts of formate are likely more stable? You usually need formic acid and heat to generate hydrogen.
Formate does indeed act as a reducing agent under appropriate conditions, but its byproduct is typically CO2 gas, not formaldehyde (HCOO- -> CO2 + H+ + 2e-). Aldehydes are generally unstable with respect to disproproportionation and are therefore unlikely reaction products.
Organoaluminum compounds are molecules with direct Al-C bonds, whereas these are effectively normal ionic salts with some unusual unit cell structure. Conflating DiBAl with aluminum formate is akin to conflating chlorine gas with clhoride anion...