That's disingenuous. There is plenty of libertarian literature on negative externalities. Milton Friedman, notably, was happy to use taxes and regulations to protect the environment.
The reasoning is simple: by polluting my land / poisoning me with PFAS, you have violated the NAP. This kind of pollution is illegal in "Libertopia".
The same can be said about your arbitrary argument. Why are the fine schedules set to $X today instead of $X+1? Why do we get drivers licenses at 16 instead of 17? Do you oppose Obamacare because it has such an arbitrary income limit?
Everything about the specific implementation of laws is arbitrary. The important thing is that it is reasonable, and on solid moral ground. A libertarian government would scale the fines / punishment / taxes in accordance with how grevious the crime was.
I am exactly not expecting unanimous consensus, which is why statements like "this kind of pollution is illegal in Libertopia [because of NAP]" seem dubious to me.
It's a lot like cryptocurrency and DAO schemes: it turns out to be really really hard to get people to accept that a bug in the law means a bad outcome for them, and nobody writes non-trivial bug-free code.