There are people who think that trans people are simply non-trans people with psychological illness, for example. Regardless of whether or not that is true or false, it is a point of fact that people with those beliefs definitely exist, and that they reject such social constructs as non-ill trans people existing, so asserting that they do (which is what publishing an OS with such emoji in it implicitly does) is a political act (in conflict with the beliefs of those people).
If everyone agreed on all social constructs and narratives, then nothing would be "political". Given that no two people share precisely the same mind and context and social constructs, every action that involves other people or society in some way is political.
Abstractions are leaky.
And also because opposing political groups are using it as a dividing line. Though interestingly, left-wing radical feminists have been consistently the most critical, which is at odds with most others who identify as left-wing politically.