Symfony2 and Lithium are two frameworks I can currently think of that use them extensively. On the one hand, Symfony2 has a quite extreme implementation, and on the other, Lithium's is much more concise. The backslashes can be used to represent a hierarchy.
Double colon is already being used for static member referencing, and in a few talks I've heard from Rasmus, they weren't able to find a way to overload it for Namespaces.
Another option that was discussed was a triple colon operator, which most were opposed to b/c of it's length. I personally think the backslash is ugly, and I kind of like the triple colon operator better b/c of it's similarity to the double colon operator. Regardless of which one is prettier, I wish the double colon operator could have been overloaded.
I hope I'm stating this right, I must admit it's from a fuzzy recollection.
Not only that, it's very unconfortable to type in some international keyboard layouts.
It's the main reason why, even though my phyiscal keys are in German layout, I still have the USA layout in software. It's just nice to be able to make [] with a single key press :)