More likely, Ukraine after the war will be a massively destroyed country, with widespread poverty and a constant need for western powers to pour money into - and that breeds corruption. The only way forward - should they survive as a nationstate - would be some kind of grotesquely enlarged Marshall Plan - they would become in the 21th century that what Germany was between 1946 and 1990: A military bridgehead and designated battlefield should Russia get another taste for war, with modest economic growth.
Still, most countries had rebuilt their economy to pre-war levels before 1955, and in many cases around 1950.
Given the very small size of Ukraine's economy, reaching their pre-war level will not take very much. Should they, as I predict, come out of the war as a united nation, able to get rid of most of the corruption, they may be able to massively outperform their pre-war gdp fairly quickly.
If they return to pre-war levels of corruption, no amount of economic aid will bring their economy to western levels.
When the war is over, it may be that the new-found unity caused by the external threat will be enough for them to reinforce their institutions significantly. This could reach a point that could ensure lasting democracy while enabling them to properly fight/eliminate most corruption. At that point, combined with a peace treaty with Russia, they should be able to Join.