There doesnt appear to be any claim that this undesired software was being run on any other account besides the managed one.

Depends. In the Active Directory world, policies can be applied at the user or computer level. Not sure about Chrome OS, but computer level policies absolutely can effect other users. I bet if OP signed into a normal, non-Google Classroom/organization affiliated account after they reset the device, they wouldn't have found GoGuardian running. This seems like if you connected an arbitrary device to a Windows domain over say VPN, then got surprised when user level policies were applied to the profile created on the local machine resultant from the process of connecting a machine to a domain. This is very much by design of ChromeOS as other commenters point out.