Vim is not for me, I unzip the epub/docx and then open the xml/html files in Kate, I had to do this to examine what is saved or how it saved or if my custom epub exported worked correctly. For epub I think you need to make sure the metadata file is the first one in the archive for it to work(so not sure if editing stuff directly in vim will preserve the order)
The xml will probably need to be run through a formatter to be readable. You can type `:%!xmllint --format -` if you have xmllint installed.
Now prepare to spend several hours trying to make sense of the xml. :-p