I don't think that is possible (to re-create that feeling of awe) on a single screen computer. Perhaps some VR room, but then again most people do not have such special hardware.

What I can see might be useful is a traditional Web space that creates a lesser but similar "flavor" of the awe by showing plenty of book titles while letting you navigate in different directions like you would wonder along the shelves in a physical library. At least such a low tech Web version can be consumed from less than wealthy countries.