Sources of Power by Gary Klein is an absolutely fascinating book for leaders, and covers this topic in depth: how experts use intuition and how they work to articulate and distribute that to others to build up similar expertise.

Just two of the interesting observations...

Experts conduct better pre-mortems - that is, given scenarios where eventually something failed, they are able to more accurately predict which parts of the scenario contributed to the failure.

And experts are "two steps ahead" in troubleshooting - which makes it (paradoxically) harder to convince others their direction is correct.

Anyway, great book on the topic, essential reading in my mind.