What made his interviews interesting is that he, apart from the mentioned standard hitching points, was inquisitive and unafraid to ask 'stupid' questions. Those often gave the guest room to delve into his or her subject of expertise, enlightening the listener and Rogan at the same time. Only a few of the guests were scientists, most were comedians, MMA fighters, ex-servicemen and such. Things might have changed since then but I can not imagine him ever labelling anything he does as 'science'.
[1] this period ended when he sold out to Spotify
He does like 3-5 episodes a week, and they're each 2-4 hours. So there's a shitload of content, much more than I could ever sit through. When I was commuting ~3 total hours each day, podcasts were my medium of choice, I would generally listen to maybe one of his podcasts per week and skipped the other 2-4 after listening long enough to know that I didn't give a shit about the guest, whether it's because they were a quack, some random boring comedian, or some meathead MMA person.
He is (rightly) criticized for having lots of shitty guests on, and that criticism is fair. But the fact that the podcast is often bad doesn't mean that it's always bad. When the podcast is at its best, it is very, very good.
On the website the episodes are broken down by category, so if you want science content you just click "scientists". Unfortunately Joe is too dumb to tell the difference between the real scientists and the fake ones, so most of the quacks are lumped in there too.