It is possible to acquire an unassailable monopoly over PoS tokens. You might be able to buy scraps from random traders, but will the >51% whale be willing to sell their core holdings when they can simply live off their staking yield?
>A permissioned blockchain is one in which the ability to add blocks is limited to a certain collection of entities
I agree. Ripple is an example of a chain which explicitly follows that model. PoS regresses to something like this because a 51% majority attacker can control consensus.
Is ASIC hardware made of silicon? In that case, an entity who owns the entire supply of silicon has a "permanent, unassailable monopoly over ASIC hardware in general".
Silicon is the second most abundant element in the Earth's crust, after oxygen: and only because there are two oxygens in silicon dioxide.
If someone corners the market on silicon, Bitcoin dominance is the least of our problems.
But physical capital is also finite.
Followed through to its ultimate conclusion, a set of trusted entities should simply run some kind of performant database.
This is an incorrect explanation of what a permissioned blockchain is. A permissioned blockchain is one in which the ability to add blocks is limited to a certain collection of entities whose public keys are hard coded into the blockchain's consensus mechanism. We don't say that needing to buy tokens constitutes needing "permission" any more than you need permission from a chip manufacturer to buy ASICs to mine a PoW cryptocurrency.