Say I have $1M in the bank (or in Bitcoin), but I owe the IRS say $300K.
I leave the country, and take my money out of the reach of the IRS.
My "net worth" on an accounting statement might be $700K, but if I'm making a point of avoiding and biting my thumb at the IRS, I still absolute have access to $1M, regardless of moneys owed or claimed. And if I have no intention of paying those taxes, I'm certainly going to use that money. And McAfee was very actively saying "I'm keeping that owed tax and doing whatever the hell I like with it".
According to [0] he was down to about $4M in net worth after 2008, which isn't nothing, especially in a LCOL country, but for context, if he made 200k per year and put 10% away for retirement from when he was 25, he would have had the same amount.
[0] https://www.therichest.com/celebnetworth/celebrity-business/...
We are assuming McAfee is just not paying taxes because craziness, but when you have volatile situation you can get burned by the rules pretty badly.
If you spend a lot of money without paying your taxes, you still owe those taxes, which means you have significantly less money than you think you do. So when his aforementioned wealth peaked at $100M, the real value (i.e. minus taxes) was probably much lower.