PM2.5 is easy to maintain with HEPA filters.
CO2 is not easy to maintain without forced ventilation, and really I would like to try inside levels lower than outside levels. (say 300 ppm)
There’s something like 50x as much oxygen in the atmosphere as co2 so a relative change of 1% nominal value will correct itself fifty times faster for oxygen than for co2 between outside and inside (ok a wild simplification, but still)
The result is that without really intense sealing it’s basically impossible to make a difference in indoor oxygen levels whereas with even a cracked window i can maintain co2 levels two to three times outdoor concentrations in my apartment.
Running a co2 fixer with the place shut up would be more like... running the air conditioner full blast with the place shut up. Yes there would be losses but they would be relatively contained.
You would need to consider the occupant oxygen consumption. A typical human respiratory quotient is 0.8 (0.8 mole of CO2 produced for every 1 mole of O2 consumed). You’ll get a net inward movement of gas into house all things being considered.
Anyway, don’t do if. If you do it ‘right’ the argon will slowly build up and you’ll asphyxiate. Thankfully achieving that level of seal is very difficult.
If you are really worried about PM2.5, just wear a PAPR.