Countries other than the UK had done that step (for currency) centuries before Britain too.
Here is some background: "How Britain converted to decimal currency" -- https://www.bbc.com/news/business-12346083
Also,
> the benefit wasn't for humans (who prefer working in 12's)
I'm not sure what people you know, I don't know anyone who would prefer base 12. That seems like a very bold claim to me - I think I would like to see some evidence for it.
If you divide the day in 10, let's call it decile, you would say see you in a decile instead of 2.43 hours.
As a side effect, 2.43h is actually 2h and less than 30 minutes and not 2h and 43 minutes (unintuitive), while 0.41 decile would probably be 41 centile, so conversion would be easier.
It is clear that illiterate people could work in "old money" fine. I suspect this is like the darts players who can do the mental arithmetic involved in a darts match fine, but would consider themselves "bad at maths". It's a learning cliff, but like any learning cliff, it no longer matters once you've climbed it.