If you hit the poorest, you won't get a ecological paradise, you'll eventually get the next iteration of an autocratic dictatorship (either left-wing or right-wing) - now with the extra support of the industry. No-one needs that.
(Electric cars might be the best alternative in rural and even some suburban areas. But they don't belong in a city.)
The reason diesel engines have been prohibited in certain city centers is because they have been shown particulary bad for people's health [0]. That is usually also something that hits the poorest people hardest. Rich people choose to live somewhere else.
Your last paragraph is just non sequitur. If you want to, you can try to explain why you think that would be the case.
[0] https://www.theguardian.com/environment/2017/may/15/diesel-e...