If you were a member of AWU, that would very much be a legitimate issue to bring to your workplace unit chair.
AWU does advocate for the interests of workers, as demonstrated by this article. It's just that full-time employees don't tend to have as many issues as the temps do.
If I worked at Google and I had some complaint about my health insurance or something, it doesn’t seem like the union would even be the right people to talk to, because they don’t seem to represent the well-being of the workers like an ordinary union.