Looking at it purely from an efficiency perspective, encouraging biological weapon development in humans at a rapid pace - possibly through retroviral techniques - may be more effective than technological devices, if the former is less detectable than the latter, and especially if the former has a lower price point than the latter.
There are multiple variables in play here, and that's not even getting into the ethical considerations.
E.g. - why research a gun when you could brain someone with a big rock?
Seriously, not trying to be condescending here - if you could probably do a thing more effectively down the road with one path, why would you choose a more immediate path?
> During the height of the space race in the 1960s, legend has it, NASA scientists realized that pens could not function in space. They needed to figure out another way for the astronauts to write things down. So they spent years and millions of taxpayer dollars to develop a pen that could put ink to paper without gravity. But their crafty Soviet counterparts, so the story goes, simply handed their cosmonauts pencils.
The soviets? They just gave their agents poisoned dentures and called it a day.
What would be more scalable- a human born venomous or the ability to install a venom gland in a human sinus, replacing at least one tooth?