I'm not aware of any tricks to make mile calculations easier but the fractional scale common with the inch is very useful for real-world mental calculation and practical exchange. Effectively everything is powers of two. Got something between 1/4 and 1/2 inch? Great, use 1/8ths. It's three. Not close enough? How about five 16ths? It infinitely scales to provide another unit that is suited to the measurement at hand. In some contexts you might just say you pick the closest 1/8th. In others you might use 32nds. You can use the same measuring devices to agree on an ad-hoc standard that everyone understands.

But with the metric system you only really get cm (too coarse) and mm (too fine) but you don't get something like 9/16 so you can't "work in 16ths" and have everything be whole units again.

Adjusting HVAC in degrees-C is infuriating to my Fahrenheit sensibilities. 20C is cold, 22C is hot. 21C is probably ok but really I want something like 20.5C. The comfortable range for a room is 3-5 whole units of F, but requires a bunch of fractions in C that you may not even have available on your thermostat.

Sure, converting between units is easy in the metric system. That doesn't make it the best thing to use all the time. Hell, the idea of thousandths of an inch is used commonly, so even the imperial system is base 1000 in some cases. But I've never seen anyone utilize the fractional scale with metric units, probably because the units are the wrong size for that to be useful.