If you have no programming experience whatsoever and you're looking to do web development, I recommend starting with HTML. A good book is the Head First HTML with CSS and XHTML. HTML isn't a programming language on its own but it is used in conjunction with pretty much everything else and is pretty much the starting point. That book does a really good job explaining the very basics and why you'd do something a certain way. From there, you can expand into actual programming languages afterwards.