There's also a fundamental democratic issue at stake: It's not by coincidence that the United States Capitol Police answers to the legislature and not to the executive -- indeed, this is seen around the world (e.g. Canada's Parliamentary Protective Service answers to the Speakers of the House and Senate) and arguably the principle that military forces should not be brought to the seat of legislative power dates back to the Roman Republic... which swiftly became the Roman Empire after Caesar crossed the Rubicon with an army at his back.
Let's do a thought experiment: let's say there are a few elements in the police who are active QAnon believers, sprinkled in at various levels. Let's also assume some more force members are not believers, per se, but sympathize with the cause, and are willing to look aside since they may dislike some legislators who they see as enabling BLM, Antifa and other un-American actors (in their eyes) and believe that something "weird" happened with the elections and/or the whole establishment is dirty. Would these individuals not listen to the orders of the commander in chief, even when not delivered via the official chain of command?
It's a matter of law that they answer to the legislature, this isn't an "assumption." Individually they have answered to a not very sharp police chief, and the Sergeants-At-Arms of the House and Senate, who are all in the process of resigning because of how badly they recently screwed up, if that's what you mean.
I could have expressed myself better there - I was distinguishing between them being answerable to the legislature (de jure) in the logical, org chat way, and them "answering" to a mercurial president they ideologically agree with (de facto), in the here and now.
Hmm, why turn down an offer of assistance from a military whose commander-in-chief wants to overturn the election? I can think of a few reasons...