The city you call home dictates a lot about your life -- friends, proximity to family, potential employers, culture -- and you're in the best position to find a second home after graduating. It only gets tougher as you get older.
As for the CV, well, he's right. Don't go somewhere or do something for the sake of improving your resume, unless you want to spend the rest of your life focusing on your job application.
Finally, as for jobs that pay you plenty of money...look at his audience. They're all MBAs. High-paying jobs aren't exactly scarce for MBAs. :)
Regardless, his point is not that "money rains from the sky" but that people should develop the life they want, irrespective of making money. Money will generally work itself out (whether its by making money off your passion, or working to support your passion as a hobby).