I'm not sure about immunity either though. Don't allergic reactions get worse with repeated exposure? I've always been careful about it for that reason.
I know some people who are very diligent about contact and manage to work without getting a rash. If you want to go that route you have to be very diligent. Apron, gloves, long sleeves, you don't need a mask. The problem for many people comes when their phone rings and they reach into their pocket (true story) or their nose itches. I am not that neat so I just went with it.
Are there any English language sites/communities dedicated to kintsugi that I should check out?
You can use cashew lacquer. It has its own pros and cons but isn't as nasty on the skin and overall easier to work with anyway.
That said, urushi in all its forms is one of the most amazing art forms - there are literally thousands of decorative techniques and uses.