Another fun fact, is that previously to Chrome, Google had been doing the same with the Google Toolbar for IE, which changed everyone's default search to Google as well. Chrome wasn't so much about "protecting the open web" as protecting Google: They were afraid (not inaccurately) that Microsoft was considering figuring out a way to prevent the Google Toolbar from hijacking the search settings in IE.
The nontechnical user flow at the time, was that they might have MSN Search or whatever on Internet Explorer 6, and then they'd hit a website that needed Adobe Flash Player. The Flash Player installer would have the "Also install the Google Toolbar" checkbox preselected, so it would install that browser toolbar and switch your search engine to Google.
The reason Sundar Pichai is the guy that ended up on top at Google is because the Google Toolbar (and then Chrome) was his baby, and that ushered in Google's monopoly much more than literally anything else at Google.