Let's say you came out even after 100,000 hands. If I randomly divided those hands into two sets of 50,000 each, would you expect one of those sets to be up by 10% and one of those sets to be down by 10%?
Not sure I understand your other question. There are no percentages in particular that I would 'expect', but if you ran the sim enough times then yes they'd revert to some mean. I've never done such analysis so I don't know what the results would look like.
Luck on these bigger pots has a huge impact on overall win rate, but in a set of 100,000 hands, you may only be involved in 2-3000 of them, and you may only expect to win something like 400 or 500 (very rough estimates). Maybe that helps explain why there's more variance than you might expect in a seemingly large sample.