So on the distribution side, they have a population of only 13 million, with a geographic size of 1.2 billion sq metres, which lands us at roughly a thousand times the amount of energy they need to meet the 1MWh per annum per Chad citizen. If they were harvesting it that is. (And that's using 20% efficient solar panels alone. No wind, etc.)
Chad's problem is a lack of anything to trade in exchange for the equipment to harness the sun and build the storage and distribution network. (Grid distribution infrastructure, maybe a liquid air storage facility or 3, solar panels etc) But the sun itself provides them more than enough energy to meet that 1MWh per annum per capita target.
Also, energy density is not nearly as important as you seem to fundamentally believe. It’s pretty much all about cost and availability.
In countries that use very little energy per capita, even just a single solar panel (with a small inverter and a lead acid battery) per person (or even per family) is life changing, giving them enough energy to run a small refrigerator, a light bulb, and a place to recharge their smartphone without having to go into town and pay someone.
In deep urban environments, space is definitely at a premium, but I struggle to imagine that many people are excited to set up a dirty diesel plant in the town square when air quality is already bad enough due to heavily polluting vehicles running in the city center, let alone set up a small nuclear plant, even if wealthier countries would allow such a proliferation of nuclear technology and fuels. Once the nuclear fuel is spent, then you have this extremely toxic, dangerous waste that has to be put somewhere, and those people probably have a lot of other things on their minds, so you could just be rad poisoning their town by giving them nuclear if they don’t dispose of the waste properly.
On the other hand, the rooftops are prime locations for solar panels and solar water heaters, and because 175W/m^2 of solar converted electricity is actually a ton of energy, it’s still plenty of power.
Unfortunately, cost and availability are king. Wealthy countries are happy to sell old assets at a steep discount, and so shiny new solar panels have to compete with second hand fossil fuel plants / generators that don’t lend themselves to great air quality.
Solar is an extremely sensible solution. Nuclear is not a clear answer at all for developing countries, unless you happen to have the design for a clean, portable cold fusion reactor in your pocket. Fission has a lot of problems that are manageable, but managing those problems takes significant money.
Things I've done with it. Run a Engel Cooler. Run a microwave. Boil water. Probably 1-2 gallons a day. Charge batteries for power tools. Run a skill saw. Power lights indefinitely.
With just that you're getting close to a middle class lifestyle.
Which brings up another issue, which is energy density/m2 of land. To support industrialization/high density urbanism the only fuel sources that do this are currently fossil fuels, or nuclear, but none of the renewable fuels have the energy density.
So if these countries want to increase the amount of MWh/capita, the most efficient (only?) pathway is through high-energy density fuel sources, which right now is being achieved through the use of fossil fuels. To me, this is (one of) the main reasons nuclear energy needs to be prioritized as a climate change solution.
ETA: And, now that I think about it, another way to squeeze more effectiveness from your grid is to build super energy-efficient buildings that reduces the overall and peak grid energy consumption.