https://en.m.wikipedia.org/wiki/Activation_energy
They don't necessarily bring atoms or molecules together, per se, but some do.
Here's a good example of how enzymes catalyze reactions: https://pdb101.rcsb.org/learn/videos/how-enzymes-work
The last 1/3 of this old video from Shell describes how catalytic cracking, a crucial part of oil refining, works. It covers practical reactor considerations, including getting the products out so more are formed and 'poisoning' where a catalyst's efficiency is reduced by contamination and how that's dealt with in a continuous process. https://www.youtube.com/watch?v=hC1PKRmiEvs
Just learned on Wikipedia (en/Platinum) that the 2007 Nobel price in Chemistry was awarded for explaining how that works. doi:10.1002/anie.200800480
In fact, at room temperature they don't work at all, which is exactly the problem with catalysts, they don't work when you start your car.
They need to heat with the hot combustion gases to start working, and that takes a while.
This is one of the reasons that laboratory's measurements of particles and gases like nitrogen oxides do not apply to real emissions in cities, because most people in cities will use the cars, for example, diesels in Europe, for very short periods of time, then let the car cool down and use it again to go back less than 10 kilometers away.