Proving some maps can't be colored with three colors is easy, you only need to find one and enumerate all the three-colorings and find none of them work.
It's not really a theorem about colors though, they're just labels.
Re proving any, I replied to a sibling comment. What I was imagining was the inverse - proving that you can't construct one that requires a fifth.
I recognize that this comment includes jargon, but I assume you'll Google it. I'd include diagrams but HN doesn't support them.
But, I understand and trust the mapping of the problem to a graph, so perhaps if I see why the problem is hard on a graph that should be enough for me.
But my reasoning was along the lines (but now in my newfound terminology) of:
K1 - trivially 1 colour needed. K2 - 2.
If we add another region on the map, we either have K3 or K1,2. In the latter case the third region/vertex need only be different to the one it touches, but K3 clearly needs 3 colours.
Adding the fourth region is similar, and again K4 clearly needs 4.
The fifth region touches at most 3 others, since K5 is non-planar. Thus, it can take the colour of the untouched region.
That's not very formal, but why isn't proof by induction easy from there? i.e. if we can't build a map that ever requires a fifth colour, then it can't be that there exists a map which requires more than four?
* It's easy starting from the end, just put one colour in the middle, then alternate second/third colours around the edge until you get back to the start and have to add a fourth. From construction, the worst case is from K1,2 then adding another for K1,3 at which point we need four colours already, but when we add two more on what will be the C5# around they each only connect to one each side and the center. In adding each one you can simply use the colour one hop over on the circumference.
# Since the center of K1,3 must be the center of the final C5-plus-thing, as it already had 3 spokes.
It's just that the C₅-plus-thing requires four colors, even though it doesn't contain any K₄ induced subgraphs. So we could imagine that there might be some larger planar graph that requires 5 colors without containing K₅. As it turns out, there isn't, but that's the thing that's hard to prove.
In secondary school I argued along the lines you describe, that you can mix three colours in a circle, and then a fourth around the circumference mixes only with at most two of the others - and in terms of the FCT is then a 'barrier' allowing re-use of the first three.
That's quite off-topic, but you suddenly jolted my memory of it. More on-topic, being colour-blind (never told which type and I can't work it out either) I find conversations about colours frustrating, and very strange to wonder if we see anything alike at all, or just learn to call the same physical thing alike despite perceiving it perhaps very differently.