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Re:Hiren’s BootCD Based on Windows 10 PE X64 by morpheuskafka on Friday October 11, 2019 @05:10PM (#21228505)
WinPE 10.0, the base OS of this, does not include WoW64, so it will not run Windows binaries compiled for the x86 architecture.

Using this software for gaming or similar purposes would be a violation of the Windows PE license agreement.

Re:Hiren’s BootCD Based on Windows 10 PE X64 by vulpessarl on Friday October 11, 2019 @06:27PM (#21229058)
I have a similar Windows 10 PE BootCD / USB / PXE, built from scripts from GitHub (https://github.com/VulpesSARL/MiniNT5-Tools) which includes WoW64, that allows to run 32 Bit executables.