Second, code changes over time. Assuming you inspect 100 lines of code to ensure that they don't call strtok() ... do you sprinkle comments all over as a warning to future programmers not to add any calls to strtok()?
Finally, assuming we could evaluate all of the code in a program at once, it is impractical to build non-trivial programs that way. Instead, we rely on contracts. The idea is that if a caller conforms to its end of the contract, the callee will conform to its end. This allows us to reason about correctness of some code without reading all the other code in the universe and thinking through all the potential code paths. Any function using strtok() would be presenting a rather ugly contract clause "this function destroys strtok's static state". Even worse, such a clause would be contagious, infecting any client of that function, and so on.
The same way you know a lot of other things about the codebase: By reading and understanding it. Given what strtok() is used for, it's almost always going to be working on a single context at any one time.