I set up a coworker with this, after he killed his laptop by shocking it.
That said, depending on the setup (type of ground system and electronics) it is not necessarily safe to touch the ground from an outlet!
A few years later another company kept a stack of keyboards next to a lady that kept killing hers. They start working again after a while thanks to keyboards having a nice fuse. Just rotate them until the keyboard port fried one day. She was also wearing a wool sweater, big old stone building in northern Sweden...
Yeah, I think we often forget that ground from the outlet is not necessarily local ground in the building materials (concrete and whatever)
Something something long chain molecules something something better insulators, or something. :)
Some weeks ago I was sitting at an office where everything was static (I think they did not ground the power outlets in the desks properly).
Every time I sat down I got a big hit. But one time my laptop crashed and shut down.
So back to the story: it might as well has to do with the shoes employee 2 is wearing and the way he/she walks.
Edit: from the poster on Reddit: "She wears a wool cover to stay warm."