How long have people been 'treating and removing' them? Presumably the leaves were tolerable while on the tree, yet poisonous. It doesn't seem to stop people planting them. (A lot of questions, but there are a lot of experts on here!)
Black Walnut: The Killer Tree https://www.extension.iastate.edu/news/2005/jul/070701.htm
https://en.wikipedia.org/wiki/Juglone
"Juglone is occasionally used as a herbicide. Traditionally, ...has been used as a natural dye for clothing and fabrics...and as ink. ...has also found use as a coloring agent for foods and...hair dyes. ...is currently being studied for its anticancer properties"
In fact I just spent six hours today doing that... with a rake. We had a window where the snow cover lifted just long enough. It'll rain tomorrow, then freeze and snow again later next week.
Also, I try to give the benefit of the doubt to the people outside doing this every week, but I'm extremely annoyed. I don't really have a choice; I rent and everywhere one can rent, one has to be a part of this madness. I wouldn't by choice pay someone to do this.