Again, it seems like you're talking as if there were "rules" about equity participation. You would have to have an absolutely awesome idea to make, for instance, a security researcher participate in a startup for no salary. Even if you pay one $50k, and that $50k cripples the startup and maxes out hardship for everyone else in the company, it's still a sucker deal for the researcher.
I'm using a familiar example to illustrate a point. It's a marketplace, not a secret society.
And I don't care what you're doing, if it takes 12 months to get a prototype in django, you aren't worth 80K.
Whole deal sounds to me like she didn't give a crap about long term future of the company, she just wanted to ride the funding into the ground through her paycheck. I'd bet she demanded more equity in a moment of faith, but by that point they were doomed.
She's not taking enough risk to get anything close to 35% in my opinion. It doesn't get more sweetheart that that. Too bad she was too dumb to realize that her good position could have been very good later on.