They were good at selling a product that cannot work. Imagine how much better they'd do with something that does work.
In order to get liquidity, you need to have your portfolio company have an exit, either by IPOing or being acquired. Good luck having either of those two events with an entirely worthless company. Even if you do, it's fraud and people will sue you and government investigators will kick down your door.
I think most of the other commenters here are on the right track. VCs just don't do that much diligence for early stage companies, especially if they have a compelling emotional pitch. Hell, I wouldn't be surprised if someone flagged that their technology was impossible and a partner pushed ahead with the deal just in case of a miracle. There's so much money chasing returns now that $10MM is a pittance for venture funding.