I don't actually know if it's possible to autorotate a quadcopter. I imagine you would have very little control during the transition. Quadcopters don't fly very high anyway, so there's probably little to gain from it.

ESC electronics usually doesn't support this, but I've wanted to try for many years.

autorotation requires control of blade pitch.

It certainly does in helicopters, which have large, relatively heavy blades you really don’t want to stop turning.

In a quadcopter the blades a small and light, so you could conceivably stop them and let them turn them in reverse as the airflow changes direction (from downwards to up through the blades). I think there would be real problem with control during the transition, and you’d need a lot of height to make it worthwhile.