You would not only get very drunk from that, you could damage your skin and/or catch fire, if there is a source of ignition.

There are a few liquids that would work. One example is the refrigerant HCFC-124. However, all of these liquids are chlorofluorocarbons, and cause much more damage to the atmosphere than any amount of A/C usage. Pretty much all volatile organic compounds fall into at least one of three categories: flammable, toxic, highly potent greenhouse gas.

Don't forget carcinogenic, teratogenic, corrosive, unbearably stinky, and insect pheromone.

For instance, you wouldn't want to smell like a ton of bananas all the time, or drive honeybees into a frenzy every time you pass by.

I'm comfortable pouring diluted alcohol in a glass and drinking it, not with soaking my clothes in it and covering large areas of my body in a continual bath of flammable liquid that also dries out my skin.