This guys trawls library sales, thrift stores etc. Library sales are normally run for charity and everything is 50c, the librarians have already selected the books to go into the sale so there isn't much chance of a $100 book being found. The aim of 'friends of the library' group of little old lady volunteers isn't really to invest $1000s in high tech to make a little more money.
They could pull out the ones worth >$1 after checking on Amazon and then package and ship them - but thats probably not cost effective for a library employee and getting little old ladies to spend the day packaging and shipping isn't what they volunteered for.
They could get in some minimum wage temp labor to do this once a year - but that's not really the libraries core business. It would be like having police patrol cars pick up cans by the side of the freeway for the 5c recycling (now theres a business model)
Seems to work for them. How many other independent bookstores have gone under lately? When I moved out of Cambridge last year, Lorem Ipsum was just upgrading to a new, larger facility.