Nokogiri is hands-down the best tool for dealing with XML that there is.
I have much the same experience with Python and anything significant developed in Python here ends up getting rewritten in Go.
Im not directly in the software industry though, just writing programs for data analysis in quality and safety programs. I'm sure once you can think directly in something like Go, it'd be faster to write that program first. But it decreases the cognitive load for me.
We have a bunch of Python scripts for operations work and it's rare that performance becomes a major concern (...except in/regarding Ansible). Development isn't my team's primary responsibility so this state of things is fine -- our SysEng team can grok Python pretty well, whereas with other languages I wouldn't say this is true.