As far as I understand, in terms of easy access, yes - in particular resources that on planemos tended to sink to the core as the object formed and cooled down.
> I think an orbital station is also more attractive than the Moon from a delta-V standpoint.
LEO? Not necessarily. You still need to burn your way up the pretty steep gravity well.
Both the Moon and the asteroids are vital components of expansion into the Solar System; they're interesting in different ways.
Source: https://en.wikipedia.org/wiki/Delta-v_budget#/media/File:Del...
See also this subway-style ∆v map of our system (inspired by a similar map for Kerbal Space Program): http://i.imgur.com/AAGJvD1.png. I feel it would work great as a poster on a wall.
The map really brings home the point that "Low Earth Orbit is halfway to anywhere in the Solar System".