My first language was C, back in the early 90s -- from nothing but the K&R book -- and I did learn pointers before I learned my next language (like truly grok them, have the ability to visualize the concept viscerally). When people in interviews ask me to tell them about the most technically challenging thing I've ever done, I tell them about learning pointers in C as a teenager. Taking everything in its context, nothing else in technology has gone that far in pushing my intellect.