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Re:IGN acquires Humble Bundle by jasminz on Saturday October 14, 2017 @03:45AM (#15471207)
Actually, you can (I assume you use Family Sharing). Either you or your kids Steam client needs to go "offline" and you'll be able to play games from same collection simultaneously.
Re:IGN acquires Humble Bundle by FuckOffNeemo on Saturday October 14, 2017 @05:58AM (#15471529)
I don't believe you can, as of a few weeks ago in any case.

When you drop offline, any shared library you had access to will drop off. When changing connectivity during a session, your games terminate within 5 minutes.