I don't actually understand why the same people (in general) will assert ecologies are extremely complex and we shouldn't meddle without being very careful to understand the effects, and at the same time think that the market is manageable from the top down without unintended consequences on the same order as the intended ones.
That's the part that reminds me most of the ecologists: a belief that we're fortunate enough to live in a universe perfectly constructed such that these complex dynamical systems (economies, ecologies), if only we'd stop mucking with them, would live on in magical harmony, aligning with normative notions like "merit" and "balance" and whatnot. I tend to view them both, instead, as difficult to analyze, hugely complex systems filled with all sorts of weird attractors and unstable states, which won't necessarily result in particularly great outcomes whether left alone or not.
In short, I agree that most of the people who claim to know what will happen if you intervene in a market are naive (i.e. unintended consequences are likely), but I also think most of the people who claim to know what will happen in a free market (e.g. that it will reward merit) are also naive. And most libertarians I've met fall into the latter category.