EDIT: It seems I was unclear in what I was trying to say. I wasn't criticizing multiple profiles in general; I was criticizing using multiple profiles as a replacement for containers. The way I see it, they don't substitute for each other, and they both have their own great use cases.
That's a feature!
I have observed dozens of time coworkers using their BYOD work laptpos that autocompleted porn URL. Dozens.
I use FF for work and a special Chrome profile (not the default one) for anything that shouldn't pop up in my autocomplete in front of coworkers/clients.
That way it's pretty hard to screw up...
But on Firefox it seems totally unusable because of near misses in UI. I haven't found a nice menu for switching between profiles, or a way of getting a list of available profiles short of rooting about in my settings. The default profile is can change itself in strange, and will only sometime coincide with the profile called "default".
If needed you can drag windows/tabs between profiles or even other browsers. I disabled all the referral options too.