A BOND IS A LOAN, A LEGAL OBLIGATION TO REPAY
With 100's of years of financial regulation and legal apparatus and precedence, long-standing laws, process and practices it.
It's a fundamental part of the credit system.
The price of the bond on the the markets will be a function of the coupon rate, and the 'risk' associated with the issuer actually paying back.
That's why bonds can be resold because they are worth something.
PRINTING MONEY AND SPENDING IT ON MANSIONS (or whatever) IS DILUTION
It's just making 'z dollars in circulation' no 'z*n dollars in circulation' backed by the same amount of assets, ergo, each dollar worth less.
I recommend "Investopedia.com" where you can go and look up what a 'bond' is, what a 'stock' is, what 'currency' is, and what 'central banks' do, it's a great resource.
It's definitely increasing the money supply in that case. If the assets are valuated at the correct price is another issue...
The money is both created from thin air and at the same time connected to the underlying assets in the bond.
I'm leaning towards the opinion that it's more "air" than "matter" in that case, but you could argue that it's somehow reflecting the underlying economy somehow.