I adore NK Jemisin so much, the awards are all so deserved! It was particularly nice that she won the Hugo in the midst of all the drama, too.
Another author I want to throw out there, is Liu Cixin - his novel The Three-Body Problem won the Hugo for Best Novel the year prior. Not a woman, but scifi from a vastly different cultural/racial angle than a lot of us are accustomed to, I would imagine.
(incidentally, when I picked up the book I had no idea what race or gender the author was, I was just looking for Hugo Award winners)