I'd prefer a format that distinguishes between sequences and associative arrays a bit more clearly. You can do that with S-exprs with some additional structure imposed on top, but then that gets more verbose than it has to be.
JSON is actually pretty decent, if only it had comments, richer data types, and some relaxed rules around syntax (e.g. allow trailing commas and unquoted keys).
Maybe something like EDN? https://github.com/edn-format/edn
Seems like a standardized S-expression format would fit the bill.
You could even try to make it work with existing XML tools by specifying a way to generate XML SAX events from the S-expressions.