These guys see hundreds of pitches. There's hundreds of VCs in the valley. Something can be rare--less than one in a hundred and still be likely. Rare for a single instance can be likely and expected across a large number of instances.
Accordingly, the "law of large numbers" as you report it, means that either only a handful of those hundreds of VCs in SV have witnessed inappropriate pitch behaviour, or this inappropriate pitch behaviour is not rare.
Regardless of the exact quantities, it remains true that an event is either unlikely to be witnessed, or it is not rare. That an event will be witnessed even though it is rare doesn't mean that it will be witnessed often.
The law of large numbers doesn't say that rare things happen often, is what I'm saying. Because that would be an oxymoron, not a paradox (which that "law" is meant to illustrate).
Btw, this does not compute. Those instances are "rare" but those men have "likely" witnessed them? When something is rare, most are unlikely to witness it.