I'm not a huge fan of plastics or styrofoams outside of very well-contained use cases since its breakdown in the outside into extremely small pellets is already easily detectable in our seawater-based salt supplies, and unabated, I'm not sanguine about our keeping it from pervasively entering our food supply. The actual plastic itself I'm not too happy about mainly because it represents energy waste to me, and at least those types that have phytoestrogenic effects are still debatable. The doped compounds attached to those plastics however, I'm not terribly enthusiastic about that stuff leaching out into our environment and letting the sun and weather eventually breaking them down before they materially damage our bodies.
I don't know the true manufacturing costs of sheet and block form aerogel, but they're priced so high that even multi-generational payback periods didn't pencil out even close, even granting them a 30% premium. Current manufacturers simply aren't aiming those form factors at building insulation as far as I can tell, though I'd love to be shown wrong.
For the time being, when I need near-aerogel-like qualities insulation but without the volume penalty foamed glass incurs, but can't justify the cost of aerogel due to the required quantity, I look to vacuum insulated panels to cover the big expanses of area and volume, and aerogel to fill in the gaps.
"But it's also two or three times as expensive as one of its chief rivals, extruded polystyrene (XPS), and its R-value per inch (R-3.4) is about 30% lower."