Ah - yes method impl on the cases is certainly a difference. I'd probably choose compatibility with F# sum types if this lands on the CLR though, but I can see how equality and some other things might be useful. Otherwise you are forced to pattern match for all logic which might end up like an inside out object.
They also have more configurability - while a case class provides default implementations for things like equality, you can override those (this could be a pro or a con depending on whether you prefer flexibiltiy or performance, I guess - although arguably the flexibility should only have cost if you use it, assuming it's implemented well).
It's definitely not a huge difference, and arguably Scala can suffer from it's philosophy of providing tools that can do something rather than tools for something that means the language often comes across as huge and as having too much stuff in it. I like it, but it's not the C# way right now for sure.