DevOps approach definitely shifts some sysadmin-type roles towards the development teams. That said though there are things that belong in the realm of sysadmin responsibilities - both "old school" like let's say setting up DB replication, VPNs or a puppet master server(not that "old school" but still) and "new" - things like Kubernetes and Fleet/CoreOS for example have plenty of configuration/maintenance complexity that is better suited to be handled by a dedicated sysadmin.