Its simple just to pull out your phone and grab a few seconds of sealing the box and putting on the label. Keep it for a few weeks until the transaction "settles" then delete.
The best option is to go local as a parent commenter already said. Ask the person to unbox and demo the item before you pay. If the product doesn't clearly work, leave without paying.
Yard sale groups on Facebook, Craigslist, and an active region-specific classifieds site if there's one in your area are good places to make such arrangements.
Don't meet at either party's home. The police station parking lot is best. Some police stations even have parking spots reserved for people who are performing transactions arranged online.
Amazon handled my claim when I was scammed by a third party Amazon seller.
However, I've gotten a LOT of scam Amazon messages. They are all the same "plz send me pictures at [poorly obfuscated email address]." I'd get 3-4 a day for a used Macbook. The scam is they get your email address by getting them to email them and then they send you a fake "shipped send now" email. Some people even go as far as just sending "shipped send now" as an Amazon message! I've reported all these and Amazon doesn't do anything about them. All they did was ding my seller account for marking too many messages as "no response required."